Synthesis and Properties of 4,5,6‐Triphospha[3]radialene | Zendy

Miyake Hideaki | Zendy; Sasamori Takahiro | Zendy; Tokitoh Norihiro | Zendy

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Synthesis and Properties of 4,5,6‐Triphospha[3]radialene

Author(s) -

Miyake Hideaki,

Sasamori Takahiro,

Tokitoh Norihiro

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200374

Subject(s) - moiety , tris , content (measure theory) , absorption (acoustics) , electron , substitution (logic) , computer science , chemistry , materials science , combinatorial chemistry , stereochemistry , physics , mathematics , composite material , nuclear physics , biochemistry , mathematical analysis , programming language

[3]Radialenes : 4,5,6‐Tris(2,4,6‐tri‐ tert ‐butylphenyl)phospha[3]radialene has been synthesized (see picture). The compound can be easily handled in air under ambient conditions, despite the [3]radialene moiety containing PC bonds, and exhibits red‐shifted absorption as well as high electron‐accepting ability. The unique electronic properties are brought about by the synergistic effect of the [3]radialene framework and the phosphorus substitution.

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