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When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes
Author(s) -
Liu Bo,
Roisnel Thierry,
Carpentier JeanFrançois,
Sarazin Yann
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200364
Subject(s) - hydroamination , catalysis , intermolecular force , alkaline earth metal , isoprene , regioselectivity , chemistry , styrene , metal , organic chemistry , molecule , copolymer , polymer
New alkaline‐earth amido complexes catalyze the regioselective intermolecular hydroamination (see scheme; Ae=alkaline earth) and hydrophosphination of styrene and isoprene with unprecedented activities. The catalytic performances increased linearly with the size of the metal.