Double Molecular Recognition with Aminoorganoboron Complexes: Selective Alcoholysis of β‐Dicarbonyl Derivatives | Zendy

Oishi Shunsuke | Zendy; Saito Susumu | Zendy

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Double Molecular Recognition with Aminoorganoboron Complexes: Selective Alcoholysis of β‐Dicarbonyl Derivatives

Author(s) -

Oishi Shunsuke,

Saito Susumu

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200304

Subject(s) - duty , scheme (mathematics) , chemistry , alcohol , double bond , combinatorial chemistry , cleavage (geology) , computer science , information retrieval , medicinal chemistry , organic chemistry , philosophy , mathematics , materials science , theology , fracture (geology) , composite material , mathematical analysis

Double duty : Aminoorganoboron (AOB) complexes recognize alcohol and β‐dicarbonyl units, and thereby facilitate chemo‐ and site‐selective alcoholysis of the latter (see scheme). The complex activates both reaction partners. This strategy enables CC, CN, and CO bond cleavage in addition/elimination reactions under near neutral pH conditions and provides a new method for functional group conversions.

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