Redox‐Active Metal‐Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries | Zendy

Nagarathinam Mangayarkarasi | Zendy; Saravanan Kuppan | Zendy; Phua Eunice Jia Han | Zendy; Reddy M. V. | Zendy; Chowdari B. V. R. | Zendy; Vittal Jagadese J. | Zendy

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Redox‐Active Metal‐Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries

Author(s) -

Nagarathinam Mangayarkarasi,

Saravanan Kuppan,

Phua Eunice Jia Han,

Reddy M. V.,

Chowdari B. V. R.,

Vittal Jagadese J.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200210

Subject(s) - cathode , alkali metal , lithium (medication) , redox , metal , ion , inorganic chemistry , materials science , lithium metal , anode , electrochemistry , chemistry , nanotechnology , electrode , organic chemistry , metallurgy , medicine , endocrinology

MOP(OF) up the lithium : Metal organic–phosphate open framework materials, for example K 2.5 [(VO) 2 (HPO 4 ) 1.5 (PO 4 ) 0.5 (C 2 O 4 )] (see scheme), are investigated as hybrid cathode materials for lithium ion batteries. The redox‐active metal center, robustness, available two‐dimensional migration pathways in the ab plane, and cavities along the c axis for the migration of the alkali metal ions allow the rapid insertion and extraction of alkali metal ions.

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