Solution‐Phase Structures of Gallium‐Containing Pyrogallol[4]arene Scaffolds | Zendy

Kumari Harshita | Zendy; Kline Steven R. | Zendy; Wycoff Wei G. | Zendy; Paul Rick L. | Zendy; Mossine Andrew V. | Zendy; Deakyne Carol A. | Zendy; Atwood Jerry L. | Zendy

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Solution‐Phase Structures of Gallium‐Containing Pyrogallol[4]arene Scaffolds

Author(s) -

Kumari Harshita,

Kline Steven R.,

Wycoff Wei G.,

Paul Rick L.,

Mossine Andrew V.,

Deakyne Carol A.,

Atwood Jerry L.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200209

Subject(s) - pyrogallol , gallium , flexibility (engineering) , phase (matter) , chemistry , zinc , nanotechnology , materials science , combinatorial chemistry , computer science , organic chemistry , mathematics , statistics

Hollow cylinders : Gallium‐ and gallium–zinc‐seamed pyrogallol[4]arene nanoassemblies were studied in the solution phase through various methods. The results reveal their rearrangement from spheres in the solid state to toroids in solution (see, for example, PgC 4 GaZn) illustrating the structural flexibility of gallium in the metal‐seamed frameworks.

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