Theoretical Evidence of the Stabilization of an Unusual Four‐Membered Metallacycloallene by a Transition‐Metal Fragment | Zendy

Roy Subhendu | Zendy; Jemmis Eluvathingal D. | Zendy; Schulz Axel | Zendy; Beweries Torsten | Zendy; Rosenthal Uwe | Zendy

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Theoretical Evidence of the Stabilization of an Unusual Four‐Membered Metallacycloallene by a Transition‐Metal Fragment

Author(s) -

Roy Subhendu,

Jemmis Eluvathingal D.,

Schulz Axel,

Beweries Torsten,

Rosenthal Uwe

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200148

Subject(s) - cyclopentadienyl complex , fragment (logic) , ring (chemistry) , transition metal , scheme (mathematics) , carbene , chemistry , electron , transition (genetics) , information retrieval , stereochemistry , computer science , organic chemistry , physics , mathematics , algorithm , catalysis , nuclear physics , mathematical analysis , biochemistry , gene

Connect five : Theoretical studies reveal that a Group 4 metal can significantly stabilize an unusual four‐membered metallacycloallene. The role of the substituents R that donate two electrons to the complex is decisive. The systems contain an unprecedented crucial MC bond in the MC 3 ring (see scheme; Cp=cyclopentadienyl, NHC=N‐heterocyclic carbene).

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