An Electron‐Rich Molybdenum–Molybdenum Quintuple Bond Spanned by One Lithium Atom | Zendy

Liu ShinCheng | Zendy; Ke WeiLun | Zendy; Yu JenShiang K. | Zendy; Kuo TingShen | Zendy; Tsai YiChou | Zendy

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An Electron‐Rich Molybdenum–Molybdenum Quintuple Bond Spanned by One Lithium Atom

Author(s) -

Liu ShinCheng,

Ke WeiLun,

Yu JenShiang K.,

Kuo TingShen,

Tsai YiChou

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200122

Subject(s) - molybdenum , bridging (networking) , ion , atom (system on chip) , crystallography , lithium (medication) , bond length , chemistry , computer science , inorganic chemistry , crystal structure , organic chemistry , psychology , parallel computing , computer network , psychiatry

Take five : A unique quintuply bonded dimolybdenum complex [Mo 2 (μ‐Li){μ‐HC(N‐2,6‐Et 2 C 6 H 3 ) 2 } 3 ] (see picture) was synthesized and characterized. The MoMo interaction includes an unexpected bridging Li + ion. Calculations indicate the bridging Li + ion does not perturb the MoMo bond length (2.0612(4) Å), but results in a relatively small effective MoMo bond order of 3.67.

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