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Back Cover: Bioinspired Five‐Coordinate Iron(III) Complexes for Stabilization of Phenoxyl Radicals (Angew. Chem. Int. Ed. 13/2012)
Author(s) -
Allard Marco M.,
Sonk Jason A.,
Heeg Mary Jane,
McGarvey Bruce R.,
Schlegel H. Bernhard,
Verani Cláudio N.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200098
Subject(s) - radical , ligand (biochemistry) , cover (algebra) , chemistry , int , photochemistry , crystallography , stereochemistry , receptor , organic chemistry , computer science , mechanical engineering , biochemistry , engineering , operating system
Electrons at the crossroads within oxidation pathways stabilize five‐coordinate, phenolate‐rich iron(III) radical complexes. In their Communication on page 3178 ff. , Verani and co‐workers report bioinspired coordination compounds that possess low local symmetry, and show experimentally as well as by computational methods that subtle changes in the ligand and electrolyte lead to distinct sequences in which the ligand‐appended phenolates are oxidized into phenoxyl species.