The Importance of Being Exchanged: [Gd III  4 M II  8 (OH) 8 (L) 8 (O 2 CR) 8 ] 4+  Clusters for Magnetic Refrigeration | Zendy

Hooper Thomas N. | Zendy; Schnack Jürgen | Zendy; Piligkos Stergios | Zendy; Evangelisti Marco | Zendy; Brechin Euan K. | Zendy

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The Importance of Being Exchanged: [Gd III 4 M II 8 (OH) 8 (L) 8 (O 2 CR) 8 ] 4+ Clusters for Magnetic Refrigeration

Author(s) -

Hooper Thomas N.,

Schnack Jürgen,

Piligkos Stergios,

Evangelisti Marco,

Brechin Euan K.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201200072

Subject(s) - lanthanide , counterion , ion , crystallography , physics , chemistry , organic chemistry

Playing it cool : Almost all of the constituent parts of the complex [Ln III 4 M II 8 (OH) 8 (L) 8 (O 2 CR) 8 ]X 4 , namely the lanthanide ions Ln 3+ , the transition‐metal ions M 2+ , the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to the magnetocaloric effect. Example in picture: Gd purple, Cu green, O red, N blue.

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