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Experimental and Theoretical Studies on the Synthesis, Spectroscopic Data, and Reactions of Formyl Azide
Author(s) -
Banert Klaus,
Berndt Christian,
Hagedorn Manfred,
Liu Hailiang,
Anacker Tony,
Friedrich Joachim,
Rauhut Guntram
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201200029
Subject(s) - azide , scheme (mathematics) , computer science , chemistry , combinatorial chemistry , information retrieval , mathematics , organic chemistry , mathematical analysis
Small is beautiful : spectroscopic proof or any other indication for the existence of formyl azide (HC(O)N 3 ) has until now been lacking. Although it liberates dinitrogen much more rapidly than homologous acyl azides, it has been prepared for the first time by four different methods (see scheme).