Characterization of the FeH Bond in a Three‐Coordinate Terminal Hydride Complex of Iron(I) | Zendy

Chiang Karen P. | Zendy; Scarborough Christopher C. | Zendy; Horitani Masaki | Zendy; Lees Nicholas S. | Zendy; Ding Keying | Zendy; Dugan Thomas R. | Zendy; Brennessel William W. | Zendy; Bill Eckhard | Zendy; Hoffman Brian M. | Zendy; Holland Patrick L. | Zendy

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Characterization of the FeH Bond in a Three‐Coordinate Terminal Hydride Complex of Iron(I)

Author(s) -

Chiang Karen P.,

Scarborough Christopher C.,

Horitani Masaki,

Lees Nicholas S.,

Ding Keying,

Dugan Thomas R.,

Brennessel William W.,

Bill Eckhard,

Hoffman Brian M.,

Holland Patrick L.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201109204

Subject(s) - hydride , crystallography , monomer , chemistry , atomic orbital , open shell , terminal (telecommunication) , metal , characterization (materials science) , molecular orbital , inorganic chemistry , materials science , molecule , electron , nanotechnology , physics , organic chemistry , telecommunications , polymer , computer science , quantum mechanics

Three's company : Iron(I) hydride complexes are presented (see picture; N blue, O red) that are the first monomeric open‐shell hydride complexes to be crystallographically verified as being three‐coordinate at the metal. Backbonding into diketiminate π* orbitals stabilizes the low oxidation state. The FeH bonding has been analyzed using electron‐nuclear double resonance (ENDOR).

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