An Iron(III)–Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide | Zendy

Hitomi Yutaka | Zendy; Arakawa Kengo | Zendy; Funabiki Takuzo | Zendy; Kodera Masahito | Zendy

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An Iron(III)–Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide

Author(s) -

Hitomi Yutaka,

Arakawa Kengo,

Funabiki Takuzo,

Kodera Masahito

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108933

Subject(s) - heterolysis , hydroxylation , hydrogen peroxide , chemistry , catalysis , radical , moiety , ligand (biochemistry) , combinatorial chemistry , alkane , peroxide , medicinal chemistry , photochemistry , organic chemistry , stereochemistry , biochemistry , receptor , enzyme

Selective oxidation : The success of the title reaction (see scheme) is caused by the strong electron donation from the amidate moiety of the dpaq ligand to the iron center (dpaq=2‐[bis(pyridin‐2‐ylmethyl)]amino‐ N ‐quinolin‐8‐yl‐acetamidate). This process facilitates the OO bond heterolysis of the intermediate Fe III OOH species to generate a selective oxidant without forming highly reactive hydroxyl radicals.

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