Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp) 2 (NCS) 2 ]⋅py | Zendy

Shepherd Helena J. | Zendy; Palamarciuc Tatiana | Zendy; Rosa Patrick | Zendy; Guionneau Philippe | Zendy; Molnár Gábor | Zendy; Létard JeanFrançois | Zendy; Bousseksou Azzedine | Zendy

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Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp) 2 (NCS) 2 ]⋅py

Author(s) -

Shepherd Helena J.,

Palamarciuc Tatiana,

Rosa Patrick,

Guionneau Philippe,

Molnár Gábor,

Létard JeanFrançois,

Bousseksou Azzedine

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108919

Subject(s) - spin crossover , phenazine , crossover , compression (physics) , antagonism , mechanism (biology) , chemistry , stereochemistry , condensed matter physics , crystallography , physics , materials science , computer science , thermodynamics , organic chemistry , quantum mechanics , biochemistry , artificial intelligence , receptor

A scissor‐like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp) 2 (NCS) 2 ]⋅py (see picture; dpp=dipyrido[3,2‐ a :2′3′‐ c ]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high‐spin to low‐spin transition under pressure.

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