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Dehydrogenation of Diamine–Monoboranes to Cyclic Diaminoboranes: Efficient Ruthenium‐Catalyzed Dehydrogenative Cyclization
Author(s) -
Wallis Christopher J.,
Dyer Hellen,
Vendier Laure,
Alcaraz Gilles,
SaboEtienne Sylviane
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108874
Subject(s) - dehydrogenation , ruthenium , diamine , chemistry , catalysis , combinatorial chemistry , medicinal chemistry , computer science , organic chemistry
Remote control : The title reaction is the first example of a catalyzed dehydrogenative cyclization (CDC) of diamine–monoboranes to give cyclic diaminoboranes. The cyclization reaction is strongly dependent on the nature of the substitution pattern at the remote amino group.