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Self‐Assembly of M 24 L 48 Polyhedra Based on Empirical Prediction
Author(s) -
Bunzen Jens,
Iwasa Junji,
Bonakdarzadeh Pia,
Numata Eri,
Rissanen Kari,
Sato Sota,
Fujita Makoto
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108731
Subject(s) - polyhedron , switchover , ligand (biochemistry) , crystallography , mixing (physics) , mathematics , materials science , physics , statistical physics , chemistry , geometry , computer science , quantum mechanics , biochemistry , receptor , operating system
Critical structural switch : A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M 12 L 24 or M 24 L 48 ). This molecular‐level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M 12 L 24 /M 24 L 48 switchover.
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