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Visible‐Light‐Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis
Author(s) -
Cherevatskaya Maria,
Neumann Matthias,
Füldner Stefan,
Harlander Christoph,
Kümmel Susanne,
Dankesreiter Stephan,
Pfitzner Arno,
Zeitler Kirsten,
König Burkhard
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108721
Subject(s) - photocatalysis , stereoselectivity , organocatalysis , alkylation , covalent bond , catalysis , chemistry , heterogeneous catalysis , carbon fibers , enantioselective synthesis , photochemistry , organic chemistry , combinatorial chemistry , materials science , composite number , composite material
Dream team : Heterogeneous inorganic semiconductors and chiral organocatalysts team up for the stereoselective photocatalytic formation of carbon–carbon bonds. However, the connection between the organic and inorganic catalysts should not be too tight: Covalent immobilization inactivates the system.