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Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF 3 and Elemental Sulfur
Author(s) -
Chen Chao,
Xie Yan,
Chu Lingling,
Wang RuoWen,
Zhang Xingang,
Qing FengLing
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108663
Subject(s) - aryl , chemistry , sulfur , catalysis , trifluoromethyl , copper , combinatorial chemistry , organic chemistry , oxidative phosphorylation , biochemistry , alkyl
Fluorinated functionality : The copper‐catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with TMSCF 3 and elemental sulfur at room temperature is described for the first time. This reaction provides a concise and efficient method for the synthesis of aryl trifluoromethyl thioethers (ArSCF 3 ) under mild conditions. Phen=Phenanthroline.