Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF 3  and Elemental Sulfur | Zendy

Chen Chao | Zendy; Xie Yan | Zendy; Chu Lingling | Zendy; Wang RuoWen | Zendy; Zhang Xingang | Zendy; Qing FengLing | Zendy

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Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF 3 and Elemental Sulfur

Author(s) -

Chen Chao,

Xie Yan,

Chu Lingling,

Wang RuoWen,

Zhang Xingang,

Qing FengLing

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108663

Subject(s) - aryl , chemistry , sulfur , catalysis , trifluoromethyl , copper , combinatorial chemistry , organic chemistry , oxidative phosphorylation , biochemistry , alkyl

Fluorinated functionality : The copper‐catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with TMSCF 3 and elemental sulfur at room temperature is described for the first time. This reaction provides a concise and efficient method for the synthesis of aryl trifluoromethyl thioethers (ArSCF 3 ) under mild conditions. Phen=Phenanthroline.

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