Rock‐Salt‐Type Crystal of Thermally Contracted C 60  with Encapsulated Lithium Cation | Zendy

Aoyagi Shinobu | Zendy; Sado Yuki | Zendy; Nishibori Eiji | Zendy; Sawa Hiroshi | Zendy; Okada Hiroshi | Zendy; Tobita Hiromi | Zendy; Kasama Yasuhiko | Zendy; Kitaura Ryo | Zendy; Shinohara Hisanori | Zendy

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Rock‐Salt‐Type Crystal of Thermally Contracted C 60 with Encapsulated Lithium Cation

Author(s) -

Aoyagi Shinobu,

Sado Yuki,

Nishibori Eiji,

Sawa Hiroshi,

Okada Hiroshi,

Tobita Hiromi,

Kasama Yasuhiko,

Kitaura Ryo,

Shinohara Hisanori

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108551

Subject(s) - salt (chemistry) , fullerene , lithium (medication) , crystallography , trigonal crystal system , crystal structure , chemistry , crystal (programming language) , materials science , type (biology) , ion , mineralogy , inorganic chemistry , geology , organic chemistry , paleontology , medicine , computer science , programming language , endocrinology

Rock solid : Fullerene‐encapsulated Li + (Li + @C 60 ) is an alkaline cation owing to the spherical shape and positive charge. Li + @C 60 crystallizes as a rock‐salt‐type crystal in the presence of PF 6 − . The orientations of C 60 (green; see picture) and PF 6 − (orange) are perfectly ordered below 370 K, and Li + (purple) hops within the cage. At temperatures below 100 K two Li + units are localized at two polar positions within each C 60 .

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