Internal Functionalization of Three‐Dimensional Covalent Organic Frameworks | Zendy

Bunck David N. | Zendy; Dichtel William R. | Zendy

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Internal Functionalization of Three‐Dimensional Covalent Organic Frameworks

Author(s) -

Bunck David N.,

Dichtel William R.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108462

Subject(s) - covalent bond , alkyl , surface modification , monomer , covalent organic framework , chemistry , polymer chemistry , materials science , organic chemistry , polymer

Thinking inside the COF: Internally functionalized, boroxine‐linked, three‐dimensional, covalent organic frameworks (COFs) can be synthesized by co‐crystallizing a truncated, trifunctional monomer with the parent tetrafunctional building block. The functionalized COFs possess accessible functional groups and a distinct interior microenvironment. In the picture the orange sphere corresponds to an alkyl chain or an allyl group in the pore interior.

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