Atom‐ and Step‐Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon–Carbon Bond Cleavage | Zendy

Liu Lantao | Zendy; Ishida Naoki | Zendy; Murakami Masahiro | Zendy

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Atom‐ and Step‐Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon–Carbon Bond Cleavage

Author(s) -

Liu Lantao,

Ishida Naoki,

Murakami Masahiro

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108446

Subject(s) - intramolecular force , alkene , cleavage (geology) , chemistry , carbon atom , asymmetric carbon , bond cleavage , stereochemistry , carbon fibers , computer science , combinatorial chemistry , catalysis , organic chemistry , algorithm , materials science , optically active , ring (chemistry) , fracture (geology) , composite number , composite material

In the nick of time : A nickel‐catalyzed asymmetric intramolecular alkene insertion reaction into cyclobutanones ( 1 ) has been developed. The reaction significantly reduces the number of steps required for the synthesis of chiral benzobicyclo[2.2.2]octenones ( 2 ).

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