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Assembly of Molecular “Layered” Heteropolyoxometalate Architectures
Author(s) -
Gao Jing,
Yan Jun,
Beeg Sebastian,
Long DeLiang,
Cronin Leroy
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108428
Subject(s) - redox , pagoda , nanotechnology , crystallography , materials science , chemistry , computer science , inorganic chemistry , algorithm
Neoclassical architecture : A new family of heteropolyoxometalates with “pagoda”‐shaped building blocks [Te n W 6 n +3 O 21 n +12 ] (6+2 n )− ( n =1, 2, 3) was discovered by adding {TeW 6 O 21 } layers on a classic {TeW 9 O 33 } fragment. Linking of the units allowed the generation of nanostructured clusters whose gross conformation is cation controlled. Studies of the redox behaviors of the multi‐layered clusters indicate that the Te IV template is redox‐active.