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Air‐Stable, Highly Fluorescent Primary Phosphanes
Author(s) -
Davies Laura H.,
Stewart Beverly,
Harrington Ross W.,
Clegg William,
Higham Lee J.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108416
Subject(s) - fluorescence , primary (astronomy) , chemistry , solid state , chloroform , metal , photochemistry , transition metal , combinatorial chemistry , nanotechnology , organic chemistry , materials science , catalysis , physics , quantum mechanics , astronomy
Light without fright : A synthetic route to fluorescent primary phosphanes (RPH 2 ) that are resistant to air oxidation both in the solid state and in chloroform solution is described. These versatile precursors undergo hydrophosphination to give tripodal ligands and subsequently fluorescent transition‐metal complexes.