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An Amine‐Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible‐Light‐Induced Activity for CO 2 Reduction
Author(s) -
Fu Yanghe,
Sun Dengrong,
Chen Yongjuan,
Huang Renkun,
Ding Zhengxin,
Fu Xianzhi,
Li Zhaohui
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108357
Subject(s) - triethanolamine , photocatalysis , formate , visible spectrum , amine gas treating , metal organic framework , photochemistry , titanium dioxide , metal , chemistry , materials science , organic chemistry , catalysis , optoelectronics , analytical chemistry (journal) , adsorption , metallurgy
Let your light shine : The photocatalytic reduction of carbon dioxide to the formate anion under visible light irradiation is for the first time realized over a photoactive Ti‐containing metal–organic framework, NH 2 ‐MIL‐125(Ti), which is fabricated by a facile substitution of ligands in the UV‐responsive MIL‐125(Ti) material (see scheme; TEOA=triethanolamine).