Upgrading Pyrolysis Oil over Ni/HZSM‐5 by Cascade Reactions | Zendy

Zhao Chen | Zendy; Lercher Johannes A. | Zendy

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Upgrading Pyrolysis Oil over Ni/HZSM‐5 by Cascade Reactions

Author(s) -

Zhao Chen,

Lercher Johannes A.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108306

Subject(s) - pyrolysis , gasoline , hydrocarbon , hydrolysis , zeolite , chemistry , catalysis , organic chemistry , cascade , hexane , dehydration , pyrolysis oil , crude oil , chemical engineering , petroleum engineering , chromatography , engineering , biochemistry

Bio‐oil to hydrocarbon oil : An active, selective, and stable catalyst (Ni supported in zeolite HZSM‐5) allows the conversion of a wide variety of CO and CO bonds in n ‐hexane‐extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C 5 –C 9 gasoline‐range hydrocarbons are obtained under mild conditions in water.

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