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Direct, Enantioselective Iridium‐Catalyzed Allylic Amination of Racemic Allylic Alcohols
Author(s) -
Lafrance Marc,
Roggen Markus,
Carreira Erick M.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108287
Subject(s) - allylic rearrangement , enantioselective synthesis , iridium , amination , catalysis , chemistry , organic chemistry , combinatorial chemistry
The direct route : Iridium‐catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio‐ and enantioselective (see scheme; coe=cyclooctene).
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