Rhodium Dinaphthocyclooctatetraene Complexes: Synthesis, Characterization and Catalytic Activity in [5+2] Cycloadditions | Zendy

Wender Paul A. | Zendy; Lesser Adam B. | Zendy; Sirois Lauren E. | Zendy

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Rhodium Dinaphthocyclooctatetraene Complexes: Synthesis, Characterization and Catalytic Activity in [5+2] Cycloadditions

Author(s) -

Wender Paul A.,

Lesser Adam B.,

Sirois Lauren E.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108270

Subject(s) - cyclooctatetraene , rhodium , cycloaddition , chemistry , catalysis , combinatorial chemistry , ligand (biochemistry) , stereochemistry , organic chemistry , molecule , biochemistry , receptor

Rh COT in the act : A Ni 0 ‐catalyzed [2+2+2+2] cycloaddition provides a high‐yielding, scalable synthesis of the ligand dinaphtho[ a,e ]cyclooctatetraene (dnCOT). dnCOT complexation with Rh I gives [Rh(dnCOT)(MeCN) 2 ]SbF 6 (see scheme), an excellent catalyst for [5+2] cycloadditions of vinylcyclopropanes and π‐systems with impressive functional group compatibility.

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