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The Elusive Tetrasulfate Anion [S 4 O 13 ] 2−
Author(s) -
Logemann Christian,
Klüner Thorsten,
Wickleder Mathias S.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108206
Subject(s) - ion , content (measure theory) , series (stratigraphy) , chemistry , computer science , information retrieval , mathematics , geology , organic chemistry , paleontology , mathematical analysis
Sulfates united : The unique tetrasulfate S 4 O 13 2− anion was observed in the structure of (NO 2 ) 2 [S 4 O 13 ] that forms in the reaction of N 2 O 5 with SO 3 . Theoretical investigations show that the anion is a stable member of the polysulfate series [S n O 3 n +1 ] 2− , which was investigated up to n =11.
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