Cooperative Ligand Effects in Phase‐Switching Homogeneous Catalysts | Zendy

Mokhadinyana Molise | Zendy; Desset Simon L. | Zendy; Williams D. Bradley G. | Zendy; ColeHamilton David J. | Zendy

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Cooperative Ligand Effects in Phase‐Switching Homogeneous Catalysts

Author(s) -

Mokhadinyana Molise,

Desset Simon L.,

Williams D. Bradley G.,

ColeHamilton David J.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108200

Subject(s) - xantphos , hydroformylation , rhodium , catalysis , amidine , ligand (biochemistry) , chemistry , homogeneous , phase (matter) , triphenylphosphine , combinatorial chemistry , organic chemistry , receptor , mathematics , combinatorics , palladium , biochemistry

It takes two : Xantphos ligands that contain amidate groups are selective for the linear versus the branched‐chain products in the rhodium‐catalyzed hydroformylation of 1‐octene. However, the catalyst only undergoes CO 2 ‐mediated phase switching in the presence of amidine‐substituted triphenylphosphine (see scheme).

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