Synthesis, Characterization, and Crystal Structure of [6]Cycloparaphenylene | Zendy

Xia Jianlong | Zendy; Jasti Ramesh | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis, Characterization, and Crystal Structure of [6]Cycloparaphenylene

Author(s) -

Xia Jianlong,

Jasti Ramesh

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201108167

Subject(s) - aromatization , characterization (materials science) , molecule , crystal structure , crystal (programming language) , strain (injury) , crystallography , materials science , nanotechnology , chemistry , stereochemistry , catalysis , organic chemistry , computer science , medicine , programming language

Strained : [6]Cycloparaphenylene, a molecule with 97 kcal mol −1 of strain energy, was synthesized. The synthetic strategy relied on two sequential oxidative dearomatization/addition sequences and a final reductive aromatization reaction (see scheme). The optoelectronic properties of [6]cycloparaphenylene were measured, and the analysis of the X‐ray crystal structure revealed a linear packing geometry reminiscent of a carbon nanotube.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research