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A Hydrocarbon‐Soluble Lithium Hydride Complex
Author(s) -
Stasch Andreas
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201108134
Subject(s) - benzophenone , reactivity (psychology) , lithium hydride , lithium (medication) , hydride , chemistry , hydrocarbon , cube (algebra) , inorganic chemistry , photochemistry , medicinal chemistry , organic chemistry , ion , medicine , alternative medicine , pathology , ionic bonding , endocrinology , mathematics , combinatorics , hydrogen
LiH‐ghtweight : The title complex having a central (LiH) 4 cube has been prepared and structurally characterized (see picture). The compound is stable towards LiH elimination at room temperature in solution, and can be employed for hydrolithiation reactivity as has been demonstrated by its reaction with benzophenone.