Magnetic Ordering in Self‐assembled Materials Consisting of Cerium(III) Ions and the Radical Forms of 2,5‐TCNQX 2  (X=Cl, Br) | Zendy

BallesterosRivas María | Zendy; Zhao Hanhua | Zendy; Prosvirin Andrey | Zendy; Reinheimer Eric W. | Zendy; Toscano Rubén A. | Zendy; ValdésMartínez Jesús | Zendy; Dunbar Kim R. | Zendy

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Magnetic Ordering in Self‐assembled Materials Consisting of Cerium(III) Ions and the Radical Forms of 2,5‐TCNQX 2 (X=Cl, Br)

Author(s) -

BallesterosRivas María,

Zhao Hanhua,

Prosvirin Andrey,

Reinheimer Eric W.,

Toscano Rubén A.,

ValdésMartínez Jesús,

Dunbar Kim R.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107938

Subject(s) - cerium , lanthanide , tetracyanoquinodimethane , ribbon , ion , polymer , materials science , crystallography , chemistry , nanotechnology , inorganic chemistry , molecule , organic chemistry , composite material

Ribbon‐like coordination polymers composed of Ce III ions and TCNQX 2 (TCNQ=tetracyanoquinodimethane; X=Cl, Br), but not TCNQ radicals, show unexpected magnetic ordering (see picture; Ce green). This behavior reveals remarkable subtlety for magnetic properties of lanthanide–organic materials.

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