Inverse and High CO 2 /C 2 H 2  Sorption Selectivity in Flexible Organic–Inorganic Ionic Crystals | Zendy

Eguchi Ryo | Zendy; Uchida Sayaka | Zendy; Mizuno Noritaka | Zendy

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Inverse and High CO 2 /C 2 H 2 Sorption Selectivity in Flexible Organic–Inorganic Ionic Crystals

Author(s) -

Eguchi Ryo,

Uchida Sayaka,

Mizuno Noritaka

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107906

Subject(s) - sorption , selectivity , ionic bonding , inorganic chemistry , crystal (programming language) , chemistry , inverse , materials science , ion , organic chemistry , adsorption , catalysis , geometry , mathematics , computer science , programming language

Highly selective CO 2 sorption and inverse CO 2 /C 2 H 2 sorption selectivity (4.8 at 278 K, 100 kPa) were achieved with an organic–inorganic ionic crystal. The key for the high affinity toward CO 2 is the combination of structural flexibility and strong binding sites (K + ) characteristic of organic–inorganic ionic crystals.

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