An Unsymmetrical bis CC Agostic Heterobimetallic Lithium Yttrium Complex | Zendy

Escudié Yannick | Zendy; Dinoi Chiara | Zendy; Allen Olivia | Zendy; Vendier Laure | Zendy; Etienne Michel | Zendy

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An Unsymmetrical bis CC Agostic Heterobimetallic Lithium Yttrium Complex

Author(s) -

Escudié Yannick,

Dinoi Chiara,

Allen Olivia,

Vendier Laure,

Etienne Michel

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107870

Subject(s) - agostic interaction , yttrium , lithium (medication) , character (mathematics) , covalent bond , crystallography , chemistry , mathematics , geometry , organic chemistry , psychology , psychiatry , metal , oxide

Two better than one! The structural distortions in a bis(cyclopropyl) heterobimetallic lithium yttrium complex can be interpreted as two types of CC agostic interactions (see structure), one with a more covalent character with Y, the other with a more electrostatic character with Li. The CC agostic interaction with Y is reinforced by a CH agostic interaction.

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