Premium
Preparation of 2‐Azarhodacyclobutanes by Rhodium(I)–Olefin Oxidation
Author(s) -
Dauth Alexander,
Love Jennifer A.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201107669
Subject(s) - rhodium , olefin fiber , mass spectrometry , chemistry , content (measure theory) , nuclear magnetic resonance spectroscopy , organic chemistry , information retrieval , computer science , catalysis , chromatography , mathematics , mathematical analysis
AmAZAing metallacycles : Azarhodacyclobutane was prepared by oxidation of Rh I –olefin complex 1 (see Scheme; Ts= p ‐toluenesulfonyl). Both isomers 2 a and 2 b were isolated and characterized by NMR spectroscopy and mass spectrometry; their configurations were unambiguously established by NOE experiments.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom