Crystallographic Snapshots of the Bond‐Breaking Isomerization Reactions Involving Nickel(II) Complexes with Hemilabile Ligands | Zendy

Machan Charles W. | Zendy; Lifschitz Alejo M. | Zendy; Stern Charlotte L. | Zendy; Sarjeant Amy A. | Zendy; Mirkin Chad A. | Zendy

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Crystallographic Snapshots of the Bond‐Breaking Isomerization Reactions Involving Nickel(II) Complexes with Hemilabile Ligands

Author(s) -

Machan Charles W.,

Lifschitz Alejo M.,

Stern Charlotte L.,

Sarjeant Amy A.,

Mirkin Chad A.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107620

Subject(s) - isomerization , nickel , crystallography , chemistry , octahedron , ligand (biochemistry) , solid state , photochemistry , stereochemistry , crystal structure , catalysis , organic chemistry , biochemistry , receptor

Freeze‐frame : Octahedral and square‐planar structural isomers, representing the two “end states” in a hemilabile ligand bond‐breaking isomerization reaction, have been characterized in solution by spectroscopic methods and in the solid state by X‐ray crystallography (see picture: Ni green, C gray, P orange, N blue, S yellow).

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