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High Propene/Propane Selectivity in Isostructural Metal–Organic Frameworks with High Densities of Open Metal Sites
Author(s) -
Bae YounSang,
Lee Chang Yeon,
Kim Ki Chul,
Farha Omar K.,
Nickias Peter,
Hupp Joseph T.,
Nguyen SonBinh T.,
Snurr Randall Q.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201107534
Subject(s) - isostructural , propane , propene , selectivity , metal , metal organic framework , adsorption , inorganic chemistry , chemistry , materials science , catalysis , organic chemistry , crystal structure
Two go in, one comes out : A series of isostructural M‐MOF‐74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co‐MOF‐74 exhibits the highest thermodynamic C 3 H 6 /C 3 H 8 selectivity (ca. 45) reported for any MOF to date.