Influencing the Symmetry of High‐Nuclearity and High‐Spin Manganese Oxo Clusters: Supramolecular Approaches to Manganese‐Based Keplerates and Chiral Solids | Zendy

Zhang Lei | Zendy; Clérac Rodolphe | Zendy; Heijboer Pierre | Zendy; Schmitt Wolfgang | Zendy

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Influencing the Symmetry of High‐Nuclearity and High‐Spin Manganese Oxo Clusters: Supramolecular Approaches to Manganese‐Based Keplerates and Chiral Solids

Author(s) -

Zhang Lei,

Clérac Rodolphe,

Heijboer Pierre,

Schmitt Wolfgang

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107358

Subject(s) - supramolecular chemistry , manganese , chirality (physics) , crystallography , cluster (spacecraft) , symmetry (geometry) , chemistry , supramolecular chirality , supramolecular assembly , materials science , crystal structure , stereochemistry , nanotechnology , physics , computer science , symmetry breaking , organic chemistry , mathematics , quantum mechanics , geometry , chiral symmetry breaking , nambu–jona lasinio model , programming language

Meet me at the symmetry gates : A supramolecular approach using chlorides as structure‐directing ligands gives high‐nuclearity, mixed‐valent Mn coordination clusters with {Mn II Mn III 12 }, {Mn II 3 Mn III 10 }, and {Mn II 3 Mn III 11 } core structures that have supramolecular chirality. The {Mn II Mn III 12 } complex (see structure: Mn blue, Cl green, O red) is the first structurally characterized Mn‐based Keplerate and has one of the highest symmetries reported for a high‐nuclearity Mn coordination cluster.

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