Premium
Extrusion of CO from Aryl Ketones: Rhodium(I)‐Catalyzed CC Bond Cleavage Directed by a Pyridine Group
Author(s) -
Lei ZhiQuan,
Li Hu,
Li Yang,
Zhang XiSha,
Chen Kang,
Wang Xin,
Sun Jian,
Shi ZhangJie
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201107136
Subject(s) - rhodium , aryl , alkyl , pyridine , bond cleavage , chemistry , extrusion , catalysis , carbon monoxide , medicinal chemistry , organic chemistry , combinatorial chemistry , stereochemistry , materials science , metallurgy
Snipping tool : The rhodium(I)‐catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for CC bond activation.