Extrusion of CO from Aryl Ketones: Rhodium(I)‐Catalyzed CC Bond Cleavage Directed by a Pyridine Group | Zendy

Lei ZhiQuan | Zendy; Li Hu | Zendy; Li Yang | Zendy; Zhang XiSha | Zendy; Chen Kang | Zendy; Wang Xin | Zendy; Sun Jian | Zendy; Shi ZhangJie | Zendy

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Extrusion of CO from Aryl Ketones: Rhodium(I)‐Catalyzed CC Bond Cleavage Directed by a Pyridine Group

Author(s) -

Lei ZhiQuan,

Li Hu,

Li Yang,

Zhang XiSha,

Chen Kang,

Wang Xin,

Sun Jian,

Shi ZhangJie

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201107136

Subject(s) - rhodium , aryl , alkyl , pyridine , bond cleavage , chemistry , extrusion , catalysis , carbon monoxide , medicinal chemistry , organic chemistry , combinatorial chemistry , stereochemistry , materials science , metallurgy

Snipping tool : The rhodium(I)‐catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for CC bond activation.

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