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Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
Author(s) -
Yamaguchi Kazuya,
Kobayashi Hiroaki,
Oishi Takamichi,
Mizuno Noritaka
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201107110
Subject(s) - primary (astronomy) , catalysis , ammonia , manganese , aqueous solution , molecular sieve , chemistry , sieve (category theory) , organic chemistry , combinatorial chemistry , mathematics , physics , astronomy , combinatorics
In the presence of a manganese oxide based octahedral molecular sieve (OMS‐2), a range of primary amides could be synthesized directly from primary alcohols and ammonia (see scheme). The observed catalysis was heterogeneous, and the recovered catalyst could be reused many times without an appreciable loss of its catalytic performance.