A Co‐Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C 82  and a Nickel Porphyrin with High Electron Mobility | Zendy

Sato Satoru | Zendy; Nikawa Hidefumi | Zendy; Seki Shu | Zendy; Wang Lu | Zendy; Luo Guangfu | Zendy; Lu Jing | Zendy; Haranaka Masayuki | Zendy; Tsuchiya Takahiro | Zendy; Nagase Shigeru | Zendy; Akasaka Takeshi | Zendy

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A Co‐Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C 82 and a Nickel Porphyrin with High Electron Mobility

Author(s) -

Sato Satoru,

Nikawa Hidefumi,

Seki Shu,

Wang Lu,

Luo Guangfu,

Lu Jing,

Haranaka Masayuki,

Tsuchiya Takahiro,

Nagase Shigeru,

Akasaka Takeshi

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201106912

Subject(s) - metallofullerene , porphyrin , nickel , crystallography , ferrimagnetism , anisotropy , electron mobility , electron , chemistry , materials science , fullerene , photochemistry , physics , optoelectronics , magnetization , optics , organic chemistry , quantum mechanics , magnetic field

Ball and plane : The structure of La@C 82 was clarified by single‐crystal X‐ray diffraction of samples co‐crystallized with [Ni II (OEP)] (OEP=octaethylporphyrin; see structure La red, N blue, Ni yellow, H pink). The charge‐carrier mobility of the co‐crystal was determined using flash‐photolysis time‐resolved microwave conductivity measurements. The material exhibited an anisotropic and high electron mobility of up to 0.9 cm 2 V −1 s −1 .

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