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Guest‐Responsive Fluorescence of Inclusion Crystals with π‐Stacked Supramolecular Beads
Author(s) -
Hinoue Tomoaki,
Miyata Mikiji,
Hisaki Ichiro,
Tohnai Norimitsu
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201106849
Subject(s) - supramolecular chemistry , fluorescence , inclusion (mineral) , luminescence , supramolecular assembly , nanotechnology , chemistry , solvent , molecule , materials science , physics , organic chemistry , optics , optoelectronics , mineralogy
Luminescent jewels : Unusually shaped fluorescent supramolecular clusters assemble into one‐dimensional π‐stacked supramolecular beads to eventually crystallize with a wide range of solvent molecules (see picture). The included solvent molecules modulate the fluorescence colors of the inclusion crystals from blue to orange‐yellow as is known for the colors of gemstones.