A Supramolecular Protecting Group Strategy Introduced to the Organic Solid State: Enhanced Reactivity through Molecular Pedal Motion | Zendy

Elacqua Elizabeth | Zendy; Kaushik Poonam | Zendy; Groeneman Ryan H. | Zendy; Sumrak Joseph C. | Zendy; Bučar DejanKrešimir | Zendy; MacGillivray Leonard R. | Zendy

Premium

A Supramolecular Protecting Group Strategy Introduced to the Organic Solid State: Enhanced Reactivity through Molecular Pedal Motion

Author(s) -

Elacqua Elizabeth,

Kaushik Poonam,

Groeneman Ryan H.,

Sumrak Joseph C.,

Bučar DejanKrešimir,

MacGillivray Leonard R.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201106842

Subject(s) - reactivity (psychology) , supramolecular chemistry , olefin fiber , solid state , acceptor , chemistry , computer science , combinatorial chemistry , polymer chemistry , organic chemistry , molecule , catalysis , physics , medicine , alternative medicine , pathology , condensed matter physics

A supramolecular protecting group strategy has been applied to achieve solid‐state photodimerizations of olefins lined with a combination of hydrogen‐bond‐donor and ‐acceptor groups. Esters were used as protecting groups to generate head‐to‐head photodimers that were readily converted into diacids. A protected olefin equipped with a stilbene unit exhibits enhanced reactivity that is ascribed to pedal motions in the solid state (orange hexagons: template: blur circles: recognition sites).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research