Platinum‐Catalyzed Direct Amination of Allylic Alcohols with Aqueous Ammonia: Selective Synthesis of Primary Allylamines | Zendy

Das Kalpataru | Zendy; Shibuya Ryozo | Zendy; Nakahara Yasuhito | Zendy; Germain Nicolas | Zendy; Ohshima Takashi | Zendy; Mashima Kazushi | Zendy

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Platinum‐Catalyzed Direct Amination of Allylic Alcohols with Aqueous Ammonia: Selective Synthesis of Primary Allylamines

Author(s) -

Das Kalpataru,

Shibuya Ryozo,

Nakahara Yasuhito,

Germain Nicolas,

Ohshima Takashi,

Mashima Kazushi

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201106737

Subject(s) - amination , phosphine , allylic rearrangement , chemistry , catalysis , organic chemistry , aqueous solution , ammonia , primary (astronomy) , combinatorial chemistry , physics , astronomy

Direct amination of unactivated allylic alcohols with aqueous ammonia was catalyzed by a Pt/phosphine complex to give the corresponding allylamines along with water as the sole by‐product. Under optimized reaction conditions, primary allylamines were obtained as major products with excellent monoallylation selectivity. cod=1,5‐cyclooctadiene.

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