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Synthesis and Methane‐Binding Properties of Disulfide‐Linked Cryptophane‐0.0.0
Author(s) -
Little Marc A.,
Donkin Jessica,
Fisher Julie,
Halcrow Malcolm A.,
Loder Jordan,
Hardie Michaele J.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201106512
Subject(s) - disulfide bond , chemistry , methane , stereochemistry , crystallography , organic chemistry , biochemistry
Into the crypt : Direct coupling of cyclotrithiophenolene gives a new class of cryptophane with labile disulfide linkages, which is the smallest cryptophane yet reported. The new cryptophane (see structure, S yellow, C gray, H light gray) is shown to bind methane or nitrogen in solution.