Sensing of Aqueous Fluoride Anions by Cationic Stibine–Palladium Complexes | Zendy

Wade Casey R. | Zendy; Ke IouSheng | Zendy; Gabbaï François P. | Zendy

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Sensing of Aqueous Fluoride Anions by Cationic Stibine–Palladium Complexes

Author(s) -

Wade Casey R.,

Ke IouSheng,

Gabbaï François P.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201106242

Subject(s) - stibine , palladium , chemistry , fluoride , antimony , cationic polymerization , denticity , aqueous solution , bromide , inorganic chemistry , medicinal chemistry , polymer chemistry , crystallography , organic chemistry , phosphine , crystal structure , catalysis , arsine

Turn on the lantern ! The stibine donor ligand of a cationic palladium complex acts as a Lewis acid and reacts with a fluoride anion to afford the corresponding fluorostiboranyl–palladium species (see scheme). Bindung of the fluoride anion to the antimony center induces a change in denticity of the triphosphine unit and leads to a bright‐orange trigonal‐bipyramidal d 8 lantern complex.

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