Thermolabile Noble Metal Precursors: (NO)[Au(NO 3 ) 4 ], (NO) 2 [Pd(NO 3 ) 4 ], and (NO) 2 [Pt(NO 3 ) 6 ] | Zendy

Wickleder Mathias S. | Zendy; Gerlach Frauke | Zendy; Gagelmann Steffen | Zendy; Bruns Jörn | Zendy; Fenske Mandus | Zendy; AlShamery Katharina | Zendy

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Thermolabile Noble Metal Precursors: (NO)[Au(NO 3 ) 4 ], (NO) 2 [Pd(NO 3 ) 4 ], and (NO) 2 [Pt(NO 3 ) 6 ]

Author(s) -

Wickleder Mathias S.,

Gerlach Frauke,

Gagelmann Steffen,

Bruns Jörn,

Fenske Mandus,

AlShamery Katharina

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201106107

Subject(s) - noble metal , palladium , platinum , oxidizing agent , thermal decomposition , inorganic chemistry , thermolabile , chemistry , metal , nitrate , catalysis , organic chemistry , enzyme

Oxidizing noble metals : Pure N 2 O 5 can oxidize elemental gold and palladium. The complex nitrates obtained by these reactions, (NO)[Au(NO 3 ) 4 ], (NO) 2 [Pd(NO 3 ) 4 ], and also the first nitrate of tetravalent platinum, (NO) 2 [Pt(NO 3 ) 6 ] (see picture for the anion: Pt gray, N green, O blue), have the potential to act as precursors owing to their high thermolability. The thermal decomposition of (NO)[Au(NO 3 ) 4 ] was elucidated in detail by several methods.

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