Stable Fluorophosphines: Predicted and Realized Ligands for Catalysis | Zendy

Fey Natalie | Zendy; Garland Michael | Zendy; Hopewell Jonathan P. | Zendy; McMullin Claire L. | Zendy; Mastroianni Sergio | Zendy; Orpen A. Guy | Zendy; Pringle Paul G. | Zendy

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Stable Fluorophosphines: Predicted and Realized Ligands for Catalysis

Author(s) -

Fey Natalie,

Garland Michael,

Hopewell Jonathan P.,

McMullin Claire L.,

Mastroianni Sergio,

Orpen A. Guy,

Pringle Paul G.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105954

Subject(s) - hydroformylation , ligand (biochemistry) , disproportionation , catalysis , hydrocyanation , chemistry , organic chemistry , rhodium , biochemistry , receptor

Ligand maps lead to treasure! The activity of complexes of fluorophosphines (R 2 PF) in catalytic hydroformylation and hydrocyanation is predicted from a ligand map. However, the instability of R 2 PF to disproportionation is well‐documented. Examples of R 2 PF ligands (see scheme) are described that are stabilized to such an extent that they can be used in catalysis and are shown to be highly effective.

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