Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry | Zendy

McLellan Ross | Zendy; Ellis David | Zendy; Rosair Georgina M. | Zendy; Welch Alan J. | Zendy

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Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

Author(s) -

McLellan Ross,

Ellis David,

Rosair Georgina M.,

Welch Alan J.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105820

Subject(s) - chemistry , transition metal , ligand (biochemistry) , atom (system on chip) , bridging (networking) , stereochemistry , combinatorial chemistry , computer science , organic chemistry , biochemistry , operating system , catalysis , computer network , receptor

New ligands : The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple σ‐bound ligands to transition metals are described. In [HCo(1,2‐ closo ‐P 2 B 10 H 10 ) 2 (PEt 3 ) 2 ] (see structure, left) the P 2 B 10 H 10 ligand coordinates to Co through one P atom, and in μ‐[1,2‐{HRu( p ‐cymene)} 2 ‐7′,8′‐ nido ‐P 2 B 9 H 9 ]‐3‐( p ‐cymene)‐3,1,2‐ closo ‐RuP 2 B 9 H 9 (right) both closo ‐RuP 2 B 9 and nido ‐P 2 B 9 cages act as bridging κP:κP′ ligands.

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