Aerobic Alcohol Oxidations Mediated by Nitric Acid | Zendy

Aellig Christof | Zendy; Girard Christophe | Zendy; Hermans Ive | Zendy

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Aerobic Alcohol Oxidations Mediated by Nitric Acid

Author(s) -

Aellig Christof,

Girard Christophe,

Hermans Ive

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105620

Subject(s) - nox , chemistry , nitric acid , catalysis , alcohol , oxygen , in situ , photochemistry , inorganic chemistry , organic chemistry , combustion

A touch of acid : Catalytic amounts of HNO 3 can trigger the aerobic oxidation of alcohols in the presence of the solid acid amberlyst‐15. The desired oxidation cycle, mediated by (H)NO x species, is in kinetic competition with the detrimental formation of N 2 O by HNO dimerization (see scheme). In situ water removal in a gas recirculation reactor increases the reaction rate and the end‐conversion by minimizing N 2 O formation and increasing the (H)NO x turnover.

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