Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst | Zendy

Bortolamei Nicola | Zendy; Isse Abdirisak A. | Zendy; Magenau Andrew J. D. | Zendy; Gennaro Armando | Zendy; Matyjaszewski Krzysztof | Zendy

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Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

Author(s) -

Bortolamei Nicola,

Isse Abdirisak A.,

Magenau Andrew J. D.,

Gennaro Armando,

Matyjaszewski Krzysztof

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105317

Subject(s) - atom transfer radical polymerization , polymerization , ethylene glycol , amine gas treating , aqueous solution , catalysis , polymer chemistry , living free radical polymerization , chemistry , radical polymerization , electrochemistry , ether , reversible addition−fragmentation chain transfer polymerization , methyl methacrylate , photochemistry , polymer , organic chemistry , electrode

Enhanced control: Electrochemically mediated atom transfer radical polymerization (ATRP) allows easy modulation of the overall rate and control of polymerization through the variation of an external applied potential, E app (see picture). This method has been successfully applied to aqueous ATRP of oligo(ethylene glycol) methyl ether methacrylate (OEOMA 475 ) catalyzed by Cu/tris(2‐pyridylmethyl)amine.

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